I know you haven't been sure about which fish to get but, if you were still swaying between a type of tetra (or harlequin or other mid-level fish) or a type of cory, best to opt for the tetra (or other mid-level fish I mention) as they're less sensitive than cories.
The type you opt for depends on what you'd like in the tank. There are advantages of different types e.g. strong colouring (green neon tetras, cardinal tetras, ember tetras if in planted tank for contrast against greenery, red phantom tetras), patterning (harlequin rasboras or espei or hengeli rasboras), strong finnage colouring to contrast with a neutral-coloured body (e.g. x-ray tetras). I also value being able to make eye contact with each of my fish, so that rules out some with a horizontal stripe that 'hides' the eye to some extent (e.g. cherry barbs) but this is less important to most folk.
If you decided to keep the larger tank for a community of mid-level fish and cories and possibly a couple of feature fish such as honey gourami or even surface dwellers such as hatchetfish, then an alternative for your smaller tank might be some dwarf puffers which might suit your water without you having to use RO water in that tank (if you were prepared to feed them snails, etc, as required).