Shoaling fish do better when you get the whole shoal at once. Harlequins also like some cover, of the sort provided by floating plants. I have the closely related Espe's rasboras and until I got some floating plants they just hid in the back corner.
Keep an eye on your ammonia level, and if it shows above zero, do a water change. If you do get ammonia showing up, check nitrite as well. That will only start a week or two after ammonia.
Lights should come on at least an hour after the curtains are opened/the room light is turned on, and at the other end either turn off an hour before it goes dark/leave the room light on for at least an hour after tank lights off. This is because of the way fish eyes work, they need a transition period of an hour between total darkness and full tank lights. That doesn't mean to have them on all that time, just avoid sudden lights on or sudden lights off whenever you have the lights on.
Fish also need the lights to be on for the same duration every day, and at the same time every day, so a timer is perfect for this - just set it for the same every day.
You don't need the blue light, though if they can be set on a different timer from the white lights, you can have them set to come on just as the white lights turn off. maybe a 5 minute overlap just in case the timers aren't in synch.
As for duration, if there are no live plants, then as long as you want, but remember that the longer the lights are on with a plantless tank the more algae that will grow.
With live plants, try 6 hours a day to start with. if the plants starts to suffer from lack of light, increase by an hour. If algae starts to go mad, try an hour less.