I have read that fluorite is quite sharp so although you have a layer on top of it you need to avoid fish that dig as they could go through the top layer. I think that rules out kuhli loaches, though kuhli owners may be able to correct me on that. I know that my stiphodons would - they excavate under things

My instinct says bristlenoses are the ones to go with, but I know one member on here
@Littlefish had problems with a male/female pair breeding incessantly so she had to separate them. Maybe a single bn or one of the other small plecs.
If you go for angels or gouramis of any species, you need slow swimming, peaceful, non-nippy fish with them. But if you want fast swimming, boisterous fish, you need to avoid slow swimming fish with long fins such as gouramis and angelfish. This is the first thing to decide - which type of fish do you want. There are plenty of slow swimmers that are fine with angels & gouramis, you just have to pick the right ones.
And an angel/gourami mix is not not advisable.
Shoaling fish. These live in groups of hundreds in the wild but it is thought that 6 is where they lose count which is why you read everywhere that the minimum number for shoaling fish is 6. However, they do better in bigger groups. So whenever there is space for them, always get more than 6.
There are two approaches to stocking a tank - minimum numbers of lots of species or big shoals of a few species. Newcomers tend to favour the first, I know I did. But after 20 odd years I am now in the second group as I have just 2 shoaling species in a 180 litre tank (though there are also a few remains of shoals from a tank I had to close)
Black ruby barbs are not a problem for slow swimming fish - their recommended tank mates include anabatids (gouramis etc). You need 6 to 8 minimum.
Congo tetra are fast swimmers which may upset fish like gouramis and angels. Though they are not known as fin nippers.
Diamond tetras should be OK as they can be kept with anabatids.
Other shoaling fish to think about besides tetras and barbs are harlequin rasboras and their slightly smaller lookalikes Espe's rasboras and hengel's rasboras; and pencilfish. The golden (beckford's) pencilfish is in the fish profiles on here and there are several other species sold in shops as well.
Personally, I would avoid rams, Mikrogeophagus ramirezi, in all its colour forms. I know that these fish have been commercially raised for many fish generations, and can be kept in wider conditions than their wild cousins, but it is not unknown for breeders to use wild fish in their breeding tanks to widen the gene pool. The offspring of these wild fish for the next several generations need soft water in the upper 20 C temp range.
Bolivian rams (M. altispinosus) are a different matter. They have a much wider hardness range and lower temp range than rams. The only difficulty with them is telling males from females, especially as the fish in shops are juveniles.
Angels aren't exactly shoaling fish but they live in loose groups in the wild. Strictly speaking they should be kept in a group of about half a dozen in an aquarium, but very few people have tanks big enough for this. The alternatives are a single angel or a
bonded pair. Just any two angels can be problematic.
Rams of both species and angelfish need to choose their own mates. We cannot buy any male and any female and expect them to get on. Two females usually co-exist with no problems. With 2 males, one will usually kill the other. And a non-bonded male/female can results in one dead fish as well.
There are two ways of getting a bonded pair. One is to buy half a dozen juveniles, wait till two pair up then rehome the rest - but where to? Some shops will agree to taking 4 back especially if two of those have also paired up as they can sell those on easily. The other way involves watching the shop tank for anything up to half an hour without moving - you have to wait till the fish forget you are there and start behaving naturally. The males will charge at each other. They don't usually make contact but they are quite obviously warning each other off. The females will just be getting on with life, which for fish means scouring the tank for tiny bits of food. If a male allows a female to remain very close to him without chasing her away, they are likely (though not guaranteed) to have bonded. When shopping for fish like this, always take someone with you. Send them to get a shop assistant while you keep your eyes on your chosen fish.
Or get cockatoo cichlids (Apistogramma cacatuoides) instead - in 240 litres you could have 1 male and up to 4 females.