Phosphates

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Offline Helen

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Re: Phosphates
« Reply #20 on: April 06, 2018, 08:04:57 PM »
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So do you actually have an algae problem because of the phosphate? Your tank looks lovely and lush. The photos don't show any algae (but I appreciate that our tanks can look different in photos)

If you've got good growth and no algae problems, I wouldn't worry about the phosphate level. It could be a sign that you are feeding a bit too much, so reducing how much you feed might eventually have an effect on the phosphate level (along with your routine maintenance)

You could keep going and work out the rate limiting factor, but it is very easy to get in all sorts of knots trying to figure out these things.

Offline fcmf

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Re: Phosphates
« Reply #21 on: April 06, 2018, 08:38:17 PM »
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That tank is so gorgeous.  8) 

Offline TopCookie

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Re: Phosphates
« Reply #22 on: April 06, 2018, 11:50:38 PM »
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You guys always have kind words to say about my tank - thank you very much indeed, that really is hugely appreciated...   :)

Helen...  no algae problems to speak of, my interest in this chemistry/biology side of things is aimed squarely at the plants with the Hygrophila Costata in particular... 

I did have algae in the first couple of weeks with the tank, but I was at the time leaving lights on for about 12 hours a day and over feeding the fish etc...  Two big changes quickly sorted the algae out, the first being to get familiar with and properly set up the lighting timer and of course reduce the photoperiod drastically (7.5 hours now) and the second thing was getting a clean up crew sorted...

The CUC began with 6 Amano shrimp, which I very swiftly fell in love with, lol, consequently adding a further six a week or so later...  Then came a juvenile Lemon Bristlenose Pleco, and finally came the first Rabbit snail, which was also followed by more Rabbit snails and a couple of Cappuccino Faunus snails...  This little crew could clean up The Lake District, I swear, lolol...   :rotfl:

Here are a couple of rare pics of my baby Lemon BN Plec... 



Offline Helen

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Re: Phosphates
« Reply #23 on: April 07, 2018, 01:48:04 AM »
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Lovely little BN Plec. Is it old enough yet to determine if it is male or female? I ask that though I still wonder whether my BN Plec is male. He has nose bristles, but they're not terribly impressive and don't seem to have grown for a few years.

Ok, so the issue may be less the phosphates and more plant health. I have a few suggestions that may or may not work in your tank. Apologies if I'm repeating anything that you've already found through your own research.

You said that you've reduced your lighting period down to 7.5 hours. Is that all in one chunk? Do you know about lighting siestas? The theory behind it is to do with gaseous exchange. In short, when plants produce oxygen it doesn't immediately disburse. Therefore the water surrounding the leaves becomes saturated with oxygen and depleted of CO2. Because the plants then use that oxygen and produce co2 when the lights are out, or at the very least the process slows down enough for the oxygen to dissipate in the water, it is considered an optimum photoperiod for aquatic plants. Like everything, this depends on the plant, but is usually in the region of about 4 hours. In tropical rivers, where a lot of fish tank plants originate, there are also a lot of overhanging trees, so when the sun is at it's peak, the aquatic plants are actually shaded. A lighting siesta aims to mimic this - it's not dark, but there's no direct light. I have found that a siesta works really well for the plants in my tank. (It also means that the lights being on coincides with me being at home more, as the siesta is when I'm at work!)

Another question is surrounding water hardness. I have soft tap water, and I initially struggled to establish many plants (and my fish -danios were suffering). About the only plants that thrived were my crypts. I found out that both fast swimming fish and fast growing stem plants have high calcium requirements. I can never remember whether it is GH or KH, but calcium is one of the chemicals that is measured to give a hardness reading. So I no longer have fast growing stem plants. But I have also dosed with calcium (as calcium nitrate because I also have really low nitrates). It is one of the additives that I am currently checking out in my new aquascape. I have previously had a hygrophilia (though not Costata) in my tank, but it is one of the plants I struggled with because it stripped my water of calcium. Because the costata looks even more like a stem plant than the one I had, my guess is that this is quite a likely possibility.

The final thought I have is to look at where all your plants originate from, especially the ones that are closest to the hygrophilia. There is a theory that plants can produce chemicals that inhibit the growth of other plants nearby. There is less known about the science of this than the other two suggestions, so it is a lot harder to work out if it is the case. My guess would be that plants that originate from different continents might be less compatible, but the opposite could also be true. I do know that crypts and vallisneria are not meant to mix well. I hoped that this would mean they would keep to their own ends of my tank. But my most onerous aquascaping maintenance task is pulling out the plantlets of both species from the others' patches.

I've not talked about root tabs etc because I have a vague feeling that I've read you mention that you use them. Though it's not impossible that I've read that in someone else's posts.

Hope this gives you some more ideas, and research topics!

Offline Sue

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Re: Phosphates
« Reply #24 on: April 07, 2018, 09:40:36 AM »
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Calcium is GH  ;)



GH = divalent metal ions; in natural water sources this is mainly calcium with some magnesium and trace amounts of other divalent metals.
KH = chemicals that buffer water against pH changes; it is virtually all carbonate and bicarbonate in natural water sources.

(Note - metals like sodium and potassium are monovalent and are not measured in GH; and metals like aluminium are trivalent and are not included either)

Offline Helen

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Re: Phosphates
« Reply #25 on: April 07, 2018, 10:00:42 AM »
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 :vcross: Grr, I thought it was the calcium that was buffering in my tank! I'll have to have another look at what is going on. So if I need to increase my Kh (buffering) do I do that by adding carbon?

Offline TopCookie

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Re: Phosphates
« Reply #26 on: April 07, 2018, 10:33:59 AM »
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Tricky judging the colour shift with GH, but my results appear to be: 

GH:  Tap - 8.8    Tank - 7.0 
KH:  Tap - 6.0    Tank - 5.0

Dunno why the drop in the tank - possibly because of the two large chunks of bogwood...?

PH:  Slap bang in between the two ranges of the API test kit, so around 7.5


The Lemon BN Plec I've had for two months and was small/young when I got her...  I tend to assume she's a lass because of the lack of bristles - which would please me actually, if she is a girl...  My best guess is that she's still a bit young to be sure and bristles could start appearing any time over the next couple of months, or not...?

Lighting in the tank was initially reduced to six hours, a figure far more appropriate for a new tank, I believe...  Has since been built back up to 7.5 hours in steps...  Tank location is deep in a corner of the living room, which is more or less west facing and does get some daylight but it's not generally strong - however, there is a shortish period when sunlight can just reach the tank and so I have improvised a posh cardboard, lol, piece that gets popped on the tank end when the currant bun starts reaching the tank (only on days when there is no cloud cover - which is quite rare at the mo...!!!)...

I have heard about the siesta thing with lighting but haven't tried it so far...  The built in timer on the tank lights only gives you the one opportunity for on/off per day and I'm not sure I trust myself enough to be consistent with manually adding a second...  At this point, I favour the consistency of photoperiod more - but that could change...

I haven't tried root tabs and suspect they're not that necessary given the John Innes #3 layer beneath the gravel and addition of liquid ferts...  I'm still in the process of finding the right balance with the ferts, having tried TNC Lite and TNC Complete...  Started out with the Complete but switched to Lite on the grounds of growing fish numbers...  Then once I started to notice the H.Costata was looking undernourished, I switched back to the Complete...  With the advent of this whole phosphate malarkey, my plan is to now switch back to the TNC Lite as it does not contain additional nitrates and phosphates...  The next stage will be to try and learn how much to dose - so far, I have been significantly under dosing and this has worked well for all the plants except the H.Costata...  Logic behind under dosing being that the tank is well stocked plus there is the super rich substrate beneath the gravel - most of my plants are root feeders btw, which has been a concious decision based on the substrate set up, itself based on Diana Walstad's writings...  Bottom line here Helen is that I'm very much at the beginning of the learning curve, generally speaking of course but especially with regards to the use of fertilisers...  I have always assumed there would be no need for root tabs and that the high CEC factor of the substrate would mean that liquid ferts should be sufficient, along with the general organic detritus in the tank etc... 

A lot of assumptions there, when it comes to fertilising, but also a fair bit of my own studying of available material etc...  Could it be that it is worth adding root tabs just around the H.Costata...?  When they were new and healthy (if you look in the Lemon BN pics - you can see how healthy the Costata was at first), the H.Costata grew like mad, got tall fast...!!!  I kinda don't want them growing any faster, would just prefer them to be healthier again...  Damned tricky this aquatic gardening lark, eh...   :D

In terms of chosen plants and their origins, I have to confess that I have paid no attention to those details and thus cannot answer for that aspect as yet...  I probably will look into that, particularly the continental thing...  I can easily accept that there may well be such a thing as a lack of harmony between certain plants in certain situations, that could be a question of entirely natural balance, or lack of, etc... 

Offline fcmf

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Re: Phosphates
« Reply #27 on: April 07, 2018, 10:46:10 AM »
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:vcross: Grr, I thought it was the calcium that was buffering in my tank! I'll have to have another look at what is going on. So if I need to increase my Kh (buffering) do I do that by adding carbon?
To raise KH from its 'baseline'/tap water level of 1, I use pieces of limestone/Tufa rock. Others use coral sand in a bag in the filter - Skittler, from recollection. Other alternatives, although they do more than just raise KH, include JBL AquaDur and Tropic Marin Re-mineral Topic. Hope that's helpful. :)

Edited to add: yes, it's Skittler - https://forums.thinkfish.co.uk/fishtank-filtration-and-cycling/coral/msg38213/#msg38213

Offline Helen

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Re: Phosphates
« Reply #28 on: April 07, 2018, 11:01:06 AM »
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I would be inclined to agree with you re root tabs. There was something at the back of my mind telling me you probably didn't need them. And as you have a Diane Walstead type planted base, I would suggest that you don't need to consider root tabs for a few years (depending on how much you follow her method and leave plant detritus in the tank)

What units are you measuring hardness in? I would suggest that the drop in hardness is because something in your tank (plants?!) is using up the nutrients that hardness measures. This could be calcium or it could be carbon. The soil substrate would have had plenty of these initially, but the fast growing stem plants (hygrophilia Costata) could have used the excess up, so that there now isn't enough to support its growth.

Of the two, the easiest one to try is carbon, with one of the liquid carbon supplements. As you're already using TNC, I think the next thing that I would try would be the TNC lite with the TNC carbon and see if that improves the hygrophilia.

It can be a lengthy process working out the right balance for a planted tank and it continues to evolve and change with plant growth, fish stock changes and substrate development. But you sound a bit like me, in that you're clearly doing lots of research and seem to enjoy the chemistry / science side of fishkeeping. So taking time to work out the details of the right balance for your tank will keep you occupied and might delay the onset of MTS. I can't stop myself thinking about tinkering with my tank, I just don't have the time to actually do much of it these days, so I've averted MTS for the mean time. (Though in another 8 years, I might be teaching my mini mes and succumb to MTS that way!)

Offline TopCookie

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Re: Phosphates
« Reply #29 on: April 07, 2018, 11:09:41 AM »
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My water supplier's website uses German degrees and gives 8.77 but I have the API GH/KH test kit...  The KH is easy to see the colour change, but I struggle with the GH colour change (I am actually colour blind but do still usually see changes in colour - just can't always tell from what to what, lol)...

In the end, I took samples of both tap water and tank water to my LFS and got them to test them for me, but to be honest, they seemed to struggle with the colour shift with the GH test too...!!!  Ended up with about three of the staff all watching closely and discussing it in detail to arrive at a common agreement  :rotfl:

With that in mind, I think it would be fair to say that my figures, and probably most people's I'd bet, are just an approximate guideline...  :)


I do have and did try the TNC Carbon...  Plants went on a massive growing spurt...!!!  Problem was that my Amano shrimp in particular went all soporific and into hiding...  It really freaked me out and I swore never to put more carbon in there...!!!  Plus I also tend to view the addition of carbon as another move away from the desired low tech priciples, and on top of that I also believe that inconsistency with carbon levels can lead to problems - once again, I'm not sure that I'd trust myself (or even want to) to dose with measured liquid carbon daily...

I am, rightly or wrongly, of the belief that we shouldn't "need" to dose with carbon, unless of course the desired goal is super fast plant growth and/or the desire for tricky plant species etc...

Offline Sue

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Re: Phosphates
« Reply #30 on: April 07, 2018, 11:30:08 AM »
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It's not carbon you need to add to raise KH - either as CO2 gas or liquid carbon - it's carbonate or bicarbonate. Some people add bicarbonate of soda (as used in cooking) but I don't like to use that as it adds sodium to the tank and there are few sources of fresh water that have much sodium (Rift Lakes excepted) so fish have not evolved to cope with it. It also increases TDS.

As fcmf says, calcium carbonate is the usual way to add buffering, and that includes limestone rocks, shells, coral etc. The mineral aragonite (rocks or sand) is also calcium carbonate. These will obviously also add calcium, therefore increase GH as well, and it will also increase pH slightly. Calcium carbonate is officially insoluble in water but it will dissolve very slowly - more so at pH under 7.
Dolomite, or dolomite sand, is better than limestone/coral/shells/aragonite, if you can find any. Dolomite is calcium magnesium carbonate not just calcium carbonate.

Offline Sue

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Re: Phosphates
« Reply #31 on: April 07, 2018, 11:37:56 AM »
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Liquid carbon is usually glutarahdehyde which is also used as an industrial steriliser. Shrimps are not happy with it and some plants can be affected as well. If it must be used with shrimps, it is much safe to user a dose rate lower than the bottle says.
https://www.cdc.gov/niosh/topics/glutaraldehyde/default.html

Offline TopCookie

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Re: Phosphates
« Reply #32 on: April 07, 2018, 11:50:22 AM »
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Blimey...!!! 

That explains a lot, thanks for that information Sue...  Just checked and yes, TNC Carbon is 2% Gluteraldahyde...

I nearly had pasteurised prawns...!!!   :yikes:


Offline TopCookie

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Re: Phosphates
« Reply #33 on: April 07, 2018, 12:26:50 PM »
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It can be a lengthy process working out the right balance for a planted tank and it continues to evolve and change with plant growth, fish stock changes and substrate development. But you sound a bit like me, in that you're clearly doing lots of research and seem to enjoy the chemistry / science side of fishkeeping. So taking time to work out the details of the right balance for your tank will keep you occupied and might delay the onset of MTS. I can't stop myself thinking about tinkering with my tank, I just don't have the time to actually do much of it these days, so I've averted MTS for the mean time. (Though in another 8 years, I might be teaching my mini mes and succumb to MTS that way!)

For sure Helen...  While not formally educated myself, I am the son of two teachers and they long ago encouraged me to be inquisitive about stuff in general...  I do like to understand things, then I find them easier to remember - never was one for having the ability to simply remember facts and figures, unless they make sense to me...  So, yes, definitely...  an understanding of things is something I feel contributes greatly to the enjoyment we get from them...  :)

Offline Helen

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Re: Phosphates
« Reply #34 on: April 07, 2018, 08:20:29 PM »
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Having said that algae isn't often due to a lack of phosphate, I've just looked up the reason for green spot algae (which I've had a recent burst of) only to find the following:

"Cause   With Estimative Index low phosphate levels often bring on a GSA outbreak" :o

I guess I'm not over feeding the fish then.

Offline TopCookie

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Re: Phosphates
« Reply #35 on: April 08, 2018, 12:00:21 AM »
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It's really quite a hard thing to be able to refrain from over feeding them, eh... 

Offline TopCookie

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Re: Phosphates
« Reply #36 on: April 08, 2018, 10:52:46 PM »
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Will do a phosphate levels test soon, now that the initial few days with PhosGuard are well on...  Only used a small'ish amount in the skimmer there, but fingers crossed it may have had a little impact... 

Offline TopCookie

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Re: Phosphates
« Reply #37 on: April 10, 2018, 10:32:21 PM »
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Did a phosphate level check yesterday and looks to be still around that 2ppm mark, although possibly on the slightly under whereas it had looked slightly over...  That could be down to test consistency though and there is certainly no big swing yet... 

That being said, the first attempt at putting Phosguard in the skimmer was a bit of a not very good thing...  Earlier this evening, I replaced the filter pad in the skimmer, popped a load of Phosguard on top and then added a second piece of filter pad on top to hold it all in place so that it will remain in the flow path a bit better... 

Anyways, I have no artistic or creative talents and this isn't exactly neat but it is a LOT better than the first attempt which was simply to place the Phosguard on top of the single filter pad, only for the water flow to push it to one side and create a perfectly round "hole" through the stuff...!!!  This is what it looks like now: 

 

Hopefully, the upper filter pad will hold the media in place and there will be a far greater contact/flow area between the water and the media now...  Results to follow in a few more days...  :)

Offline TopCookie

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Re: Phosphates
« Reply #38 on: April 16, 2018, 12:11:05 PM »
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So, phosphate levels tested this morning...  Down to 1ppm, possibly a little higher - but much nearer the 1ppm colour chart bar than the 2ppm bar...  Also re-tested tap water for confirmation and hitting the 2ppm bar distinctly...  From this, I can deduce that the Seachem Phosguard is definitely working, albeit at a gentle or slow pace... 

At this rate, I may decided to get a media bag and put some Phosguard in the main filter...  Dunno for sure yet, but that's certainly a distinct possibility... 

Offline TopCookie

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Re: Phosphates
« Reply #39 on: April 23, 2018, 10:23:32 PM »
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Phosphate levels checked this evening and now between 1ppm and 0.5ppm...  Certainly a much happier place than 2ppm plus...!!!

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